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Ferrous acetate

CAS：3094-87-9
MW:173.933
MF：C4H6FeO4

Ferrous acetate, with the chemical formula Fe(C2H3O2)2 and CAS registry number 3094-87-9, is a compound known for its applications in various industries. This compound is a green crystalline solid that is soluble in water. It is commonly used as a catalyst in chemical reactions and as a mordant in dyeing processes. Ferrous acetate is also used in the production of pigments, inks, and pharmaceuticals. It is important to handle this compound with care, as it can be toxic if ingested or inhaled. Overall, Ferrous acetate plays a significant role in various chemical processes and industries.

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Names and ldentifier
Properties
Use and Manufacturing
Safety and Handling
Msds
NMR Spectrum
Other Information
Computational chemical data
Related Questions
Realated Product Infomation

1. Names and Identifiers

1.1 Name: Ferrous acetate

1.2 Synonyms: Acetic Acid Iron(II) Salt; aceticacid,iron(2+)salt; aceticacid,iron(2++)salt; EINECS 221-441-7; Ferrousacetateanhydrous; iron acetate; iron(2+)acetate; Iron(II) acetate; irondiacetate; MFCD00058909;

1.3 CAS No.: 3094-87-9

1.4 CID: 18344

1.5 EINECS: 221-441-7

1.6 Molecular Formula: C4H6FeO4

1.7 Inchi: InChI=1S/2C2H4O2.Fe/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

1.8 InChkey: LNOZJRCUHSPCDZ-UHFFFAOYSA-L

1.9 Canonical Smiles: CC(=O)[O-].CC(=O)[O-].[Fe+2]

1.10 Isomers Smiles: CC(=O)[O-].CC(=O)[O-].[Fe+2]

2. Properties

2.1 Appearance: Solid.

2.2 Storage: Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.

2.3 Chemical Properties: off-white to light grey or light brown powder

2.4 Color/Form: Off-white to light gray or light brown

2.5 Water Solubility: Soluble in water.

2.6 StorageTemp: Inert atmosphere,Room Temperature

3. Use and Manufacturing

3.1 Description

Ferrous acetate, with the chemical formula Fe(C2H3O2)2, has the CAS number 3094-87-9. It appears as a green crystalline solid with a vinegar-like odor. The basic structure of ferrous acetate consists of one iron atom bonded to two acetate ions. This compound is soluble in water. Safety information regarding ferrous acetate states that it may cause irritation to the respiratory system if inhaled and can cause irritation to the skin and eyes upon contact. It is important to avoid exposure to high temperatures as it may emit toxic fumes. The primary hazard associated with ferrous acetate is its potential to cause environmental harm. Steps should be taken to prevent its spread into the environment, as it can contaminate soil and water sources.

Applicable Fields

Water Treatment: Ferrous acetate is commonly used as a coagulant in water treatment processes. Its purpose in this field is to help remove impurities and particles from water by causing them to clump together and settle. The mechanism of action of ferrous acetate in water treatment involves its ability to form insoluble compounds with certain contaminants, allowing them to be easily removed.

Dyeing and Printing: This chemical compound is also utilized in the dyeing and printing industry. Its purpose in this field is to act as a mordant, which helps fix dyes to fabrics and enhance their colorfastness. The mechanism of action of ferrous acetate in dyeing and printing involves its ability to form stable complexes with dyes, allowing them to bind more effectively to the fabric.

Storage

Conditions: Store in a cool and dry place.

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3.2 GHS Classification: Signal: Warning
GHS Hazard Statements
Aggregated GHS information provided by 30 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (96.67%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.

Precautionary Statement Codes
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501

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3.3 Usage: Textile dyeing, medicine, dyeing leather, wood preservative.

4. Safety and Handling

4.1 Safety Profile: Moderately toxic by subcutaneous route. When heated to decomposition it emits acrid smoke and irritating fumes. Ferrous acetate Preparation Products And Raw materials Preparation Products

4.2 Report: Reported in EPA TSCA Inventory.

4.3 Safety: Moderately toxic by subcutaneous route. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:
Xi: Irritant
Risk Statements about Ferrous acetate (3094-87-9):
R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Statements about Ferrous acetate (3094-87-9):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 Wear suitable gloves and eye/face protection.
Attention:
1. Storage: Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
2. Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Store and handle protected from air.

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4.4 Sensitive: Air & Moisture Sensitive

4.5 Toxicity

scu-rat LD50:492 mg/kg

27ZWAY Heffters Handbuch der Experimentelle Pharmakologie.

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5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity \u2013 single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor/\u2026if you feel unwell.
Storage	P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

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6. NMR Spectrum

IR : nujol mull

7. Computed Properties

Molecular Weight：173.933g/mol
Molecular Formula：C₄H₆FeO₄
Compound Is Canonicalized：True
XLogP3-AA：173.961544
Monoisotopic Mass：173.961544
Complexity：25.5
Rotatable Bond Count：0
Hydrogen Bond Donor Count：0
Hydrogen Bond Acceptor Count：4
Topological Polar Surface Area：80.3
Heavy Atom Count：：9
Defined Atom Stereocenter Count：0
Undefined Atom Stereocenter Count：0
Defined Bond Stereocenter Count：0
Undefined Bond Stereocenter Count：0
Isotope Atom Count：0
Covalently-Bonded Unit Count：3
CACTVS Substructure Key Fingerprint：AAADcYBgOAAAAAAgAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAGgAAAAAAAACAgAACCAAAAAAIAACQCAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==

8.Other Information

Usage: Iron(II) acetate is used as a mordant by the dye industry, as a catalyst in organic oxidation reactions and in carbon nanotube synthesis. It is used as a precursor in the production of other iron compounds.

Description: Iron (II) acetate is an off-white or light brown solid ionic compound of iron. It is highly soluble in water and it forms a light green tetrahydrate. Iron (II) acetate is manufactured from scrap iron and acetic acid, and it is used as a mordant by the dye industry. Ebonizing wood is one such process.
It can also be made by the reaction of ferrous oxide or ferrous hydroxide with concentrated acetic acid 。.

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Chemical Properties: off-white to light grey or light brown powder

Uses: Textile dyeing, medicine, dyeing leather, wood preservative.

General Description: Iron (II) acetate is a white or light brown solid ionic compound of iron. It is highly soluble in water and it forms a light green tetrahydrate. It is more nontoxic than iron pentacarbonyl and reactivity is better.

Manufacturing Info: Acetic acid, iron(2+) salt (2:1): ACTIVE

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10. Related Questions

: What is Ferrous Acetate and How is it Synthesized? Ferrous acetate is a white or light brown solid ionic compound. It has high solubility in water and can form a light green tetrahydrate. It is commonly used as a mordant in the textile industry. Func..; What is the pH of a solution of iron acetate? What is the pH of a 0.1M" style="position: relative;" tabindex="0" id="MathJax-Element-2-Frame" class="MathJax">0.1M0.1M solution of Fe(CHX3COO)X3" style="position: relative;" tabindex="0" id="MathJa..; Can I synthesize iron acetate like this? The oxidation state of the iron doesn't matter too much; I am just trying to make an attractive red-brown ink. Here are some instructions I prescribed to a friend. Here's an approximately decent iron..; What are the applications of Ferrous Acetate?Background and Overview[1] Ferrous acetate is an iron ion compound that is a white or light brown solid, highly soluble in water, forming a light green tetrahydrate. It can be used as a mordant dye. F..

11. Realated Product Infomation