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Isopropylmagnesium chloride lithium chloride complex

CAS：745038-86-2
MW:144.23
MF：C3H6Cl2LiMg

Isopropylmagnesium chloride lithium chloride complex, with the chemical formula C6H15Cl2LiMg and CAS registry number 745038-86-2, is a compound known for its applications in organic synthesis. This complex is formed by the reaction of isopropylmagnesium chloride (C3H7ClMg) with lithium chloride (LiCl). It is commonly used as a reagent in various reactions, such as Grignard reactions and nucleophilic additions. Isopropylmagnesium chloride lithium chloride complex is a colorless to yellowish liquid, and it is highly reactive. It is often used as a source of isopropylmagnesium chloride in the synthesis of organic compounds. This complex offers a versatile platform for the introduction of isopropyl groups into different molecules, making it a valuable tool in organic chemistry.

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Names and ldentifier
Properties
Use and Manufacturing
Safety and Handling
Msds
Other Information
Computational chemical data
Related Questions
Realated Product Infomation

1. Names and Identifiers

1.1 Name: Isopropylmagnesium chloride lithium chloride complex

1.2 Synonyms: ISOPROPYLMAGNESIUM CHLORIDE - LITHIUM CHLORIDE COMPLEX; Isopropylmagnesium chloride - Lithium chloride complex, 1.3M solution in THF, AcroSeal§3; Isopropylmagnesium chloride - Lithium chloride complex,1.3M solution in THF; ISOPROPYLMAGNESIUM CHLORIDE-LITHIUM CHLORIDE; Magnesate(1-),dichloro(1-methylethyl)-, lithium (9CI);

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1.3 CAS No.: 745038-86-2

1.4 CID: 11275082

1.5 Molecular Formula: C3H6Cl2LiMg

1.6 Inchi: InChI=1S/C3H6.2ClH.Li.Mg/c1-3-2;;;;/h1-2H3;2*1H;;/q-1;;;+1;+2/p-2

1.7 InChkey: GFRAKTLEBRSDFT-UHFFFAOYSA-L

1.8 Canonical Smiles: [Li+].C[C-](C)[Mg++]([Cl-])[Cl-]

1.9 Isomers Smiles: [Li+].C[CH-]C.[Mg+2].[Cl-].[Cl-]

2. Properties

2.1 Appearance: Clear yellow to brown to gray Solution

2.2 Chemical Properties: Clear brown solution Isopropylmagnesium chloride lithium chloride complexSupplier

2.3 Color/Form: Clear yellow to brown to gray

2.4 StorageTemp: Flammables area

3. Use and Manufacturing

3.1 Description

Isopropylmagnesium chloride lithium chloride complex, with the chemical formula C6H15Cl2LiMgO, has the CAS number 745038-86-2. It is a complex compound consisting of isopropylmagnesium chloride and lithium chloride. This complex appears as a colorless solid with no distinct odor. Its basic structure consists of isopropylmagnesium chloride and lithium chloride molecules bonded together. Isopropylmagnesium chloride lithium chloride complex is sparingly soluble in water. Safety information regarding this compound is not available.

Applicable Fields

Organometallic Chemistry: Isopropylmagnesium chloride lithium chloride complex is commonly used in organometallic chemistry. Its purpose in this field involves its ability to act as a nucleophile, participating in various organic reactions. The mechanism of action in organometallic chemistry involves the transfer of the isopropylmagnesium chloride lithium chloride complex to the reactant, leading to the formation of new carbon-carbon or carbon-heteroatom bonds.

Storage

Conditions: Store in a cool and dry place.

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4. Safety and Handling

4.1 Safety: Hazard Codes C-FRisk Statements 34-19-14/15-11Safety Statements 7/8-45-43B-36/37/39-33-16

4.2 Specification: Clear brown solution
Safety Statements:7/8-45-43B-36/37/39-33-16
7/8:Keep container tightly closed and dry
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
33:Take precautionary measures against static discharges
16:Keep away from sources of ignition - No smoking

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5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin corrosion, Category 1B

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Danger
Hazard statement(s)	H314 Causes severe skin burns and eye damage
Precautionary statement(s)
Prevention	P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response	P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/… P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage	P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

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6. Computed Properties

Molecular Weight：144.23g/mol
Molecular Formula：C₃H₆Cl₂LiMg
Compound Is Canonicalized：True
XLogP3-AA：143.9935257
Monoisotopic Mass：143.9935257
Complexity：8.9
Rotatable Bond Count：0
Hydrogen Bond Donor Count：0
Hydrogen Bond Acceptor Count：3
Topological Polar Surface Area：0
Heavy Atom Count：：7
Defined Atom Stereocenter Count：0
Undefined Atom Stereocenter Count：0
Defined Bond Stereocenter Count：0
Undefined Bond Stereocenter Count：0
Isotope Atom Count：0
Covalently-Bonded Unit Count：5
CACTVS Substructure Key Fingerprint：AAADcYhAAAAGACAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAGAAAAAAACACAAAACAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==

7.Other Information

Chemical Properties: Clear brown solution

Uses: Isopropylmagnesium chloride lithium chloride complex is a reagent for Selective Metalations. And it was used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.

8. Toltal 38 Suppliers View more

Isopropylmagnesium chloride lithium chloride complex

Hebei Yanxi Chemical Co.,Ltd

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Tel: Update Time:2024/11/14

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Lithium dichloro(1-methylethyl)-magnesate(1-)

CANGZHOU ENKE PHARMA-TECH CO.,LTD

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Tel: Update Time:2024/11/12

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Factory Supply IsopropylMagnesiuM chloride-LiCl coMplex

Amitychem Corporation

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Tel: Update Time:2023/06/28

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Wuhan Circle Star Chem-medical Technology Co.,Ltd

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Tel: Update Time:2024/11/15

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Magnesate(1-),dichloro(1-methylethyl)-, lithium (1:1)

Henan Tianfu Chemical Co.,Ltd

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Tel: Update Time:2024/11/15

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9. Related Questions

: What is Isopropylmagnesium chloride lithium chloride complex? Isopropylmagnesium chloride lithium chloride complex is a colorless or white crystalline solid, soluble in water and some organic solvents. Applications Isopropylmagnesium chloride lithium chloride c..; How to apply and prepare Isopropylmagnesium chloride lithium chloride complex? Isopropylmagnesium chloride lithium chloride complex is a transitional Grignard reagent that can be widely used in the preparation of Grignard reagents that cannot be obtained by conventional (RX+MgR..

10. Realated Product Infomation