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How would you prepare heptanoic acid using malonic ester synthesis?

How would you prepare heptanoic acid using malonic ester synthesis?
Hadley Answered Jan 17 2022

The following steps are involved in the preparation of heptanoic acid from diethylmalonate :

• Diethyl malonate is treated with NaOEt/ EtOH to generate monosodium diethylmalonate.

• Monosodium diethylmalonate is treated with n-pentylchloride to give n-C5H11CH( COOC2H5)2.

• This on acidic hydrolysis gives n-C5H11CH (COOH)2

• This on heating undergoes decarboxylation to give heptanoic acid [ C5H11CH2COOH ].

 
Heptanoic acid
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